Enantioselective alkylidenecyclopropanation of norbornenes with terminal alkynes catalyzed by palladium–phosphinous acid complexes
D. Gatineau, D. Moraleda, J.-V. Naubron, T. Bürgi, L. Giordano and G. Buono
Tetrahedron: Asymmetry
,
20
(16) (2009), p1912-1917
DOI:
10.1016/j.tetasy.2009.07.017
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unige:14704
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Pd(II)-coordinated phosphinous acids catalyzed the formal enantioselective [2+1] cycloaddition of norbornene derivatives with terminal alkynes. The absolute configuration of (+)-3aa was assigned using VCD.
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